Article | REF: K1210 V1

Water chemistry

Authors: Marie-Christine Scherrmann, Max MALACRIA, Jean-Philippe GODDARD, Cyril OLLIVIER

Publication date: November 10, 2008

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2. Reactivity in water

2.1 Pericyclic reactions

Pericyclic reactions are reactions whose atomic utilization is total, making them particularly suitable for "green" syntheses.

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2.1.1 Diels-Alder and hetero Diels-Alder reactions

As mentioned above, the study of the Diels-Alder reaction played a major role in developing the use of water as a solvent in synthesis. In fact, Diels and Alder had carried out the cycloaddition of furan and maleic anhydride in water as early as 1931. A few cases of cycloadditions...

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Reactivity in water