Article | REF: P1460 V3

Supercritical phase chromatography

Author: Didier THIÉBAUT

Publication date: September 10, 2016

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2. Chromatographic properties of carbon dioxide-based mobile phases

2.1 Thermodynamic aspect

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2.1.1 Influence of density

As in CPL, retention depends on solute-stationary phase, solute-supercritical fluid and supercritical fluid-stationary phase interactions. Solute-supercritical CO 2 interactions can be governed by varying its pressure and, hence, its density (figure 6 )

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Chromatographic properties of carbon dioxide-based mobile phases