5. Conclusion and outlook
Radical ring-opening polymerization (rROP) appears to be a promising way of meeting current and future environmental challenges, by offering a simple method for producing degradable materials. This synthesis method involves copolymerizing a cyclic monomer, mainly of the cyclic ketene acetal (CKA) or thionolactone type, with a conventional vinyl monomer to introduce cleavable bonds (of the ester or thioester type respectively) into the polymer chain backbone. A low level of labile functions is sufficient to make the latter degradable after use, while maintaining the thermal and mechanical properties of the materials during use.
While the rROP technique is now well recognized in the community as a promising solution to the problem of plastic pollution, the end-of-life of materials obtained by this method remains to be studied and improved. In the case of collectable...
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Conclusion and outlook
Bibliography
Standards and norms
- Biodégradabilité facile. - OCDE 301 - 2013
- Evaluation of the ultimate aerobic biodegradability of plastic materials under controlled composting conditions – Method for analyzing released carbon dioxide – Part 1: general method. ISO. - ISO 14855-1 - 2012
- Standard Practice for Evaluating Biofouling Resistance and Physical Performance of Marine Coating Systems. ASTM. - ASTM D6990-05 - 2011
Patents
A light-activated resin composition and its use in 3d-printing EP 21306838
Photoresist formulations 3d microprinting techniques. WO2022249002A1
Biodegradable copolymers. WO2023078534A1
Copolymer, production method thereof, and molding. JP2023025873A
Modified adsorption material for treating wastewater. CN112619619A
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