Article | REF: RE189 V1

Radical Ring-Opening Polymerization : A tool for plastic’s degradation

Authors: Yohann GUILLANEUF, Catherine LEFAY

Publication date: November 10, 2023

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3. (Bio)degradable materials

Since the 1980s, the development of ring-opening radical polymerization has made it possible to prepare degradable polymers using different families of monomers. . The use of these polymers in well-defined applications is more recent. It is essentially based on the use of CKAs, an older and therefore more mastered family, but also more recently on the use of thionolactones, which have the advantage of good reactivity with acrylate-type monomers and above all greater stability to hydrolysis, making them easier to use. In particular, this section describes the use of rROP for...

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(Bio)degradable materials