Article | REF: AM3039 V1

Physico-chemical modification of polymers by ionization

Author: Sophie ROUIF

Publication date: January 10, 2008

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3. Polymer grafting using ionizing radiation

A monomer bearing an unsaturation (double bond) of the vinyl, allyl or acrylic type can bind to a carbon chain under the effect of ionizing radiation.

Depending on the other chemical functions (or ligands) carried by the monomer, special characteristics can be permanently imparted to the support material: antiseptic properties, ion exchangers, adhesion promoters...

Different types of radiation and irradiation facilities enable the grafting of substrates in very different forms: films, textile surfaces, granules, medical devices, for example.

3.1 Radiation-graftable functional monomers

There are a large number of monomers with graftable unsaturation and a wide variety of ligand functions. Table

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Polymer grafting using ionizing radiation