Article | REF: K499 V1

The equation of state of polymers

Authors: Bernard LE NEINDRE, Patrick CANCOUËT

Publication date: November 10, 2009

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1. Isothermal compressibility equations of state

The temperature-pressure (T-P) superposition principle implies that ln (V/V 0 ), is a function of the reduced pressure P/B 0 , according to the relationship :

ln(V/V0)=f(PB0)=PB0+B12!(PB0)213!(2B12B0B2)(PB0)3
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Isothermal compressibility equations of state