Article | REF: AF6506 V1

Organometallic chemistry - Metal-carbon double and triple bonds

Author: Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015

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2. Cumulene-type compounds

Going beyond the metal-carbon double bond, the synthesis of carbene complexes containing consecutive cumulene-type double bonds has been achieved. The starting point is an alkyne ligand whose terminal hydrogen atom is stripped off to make an acetylide ligand (figure 12 ).

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Cumulene-type compounds