Article | REF: AF6504 V1

Organometallic chemistry - Oxidizing addition

Author: Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015

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4. Intramolecular oxidative addition

The oxidative addition may well be intramolecular, particularly when the 16-electron environment arises following the departure of a ligand. We have already seen the sequence of reactions [Fe2(CO)4(C5H5)2] forms from [Fe(CO) 5 ] and C 5 H 6 (cf. article of this treatise). The step described in figure...

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Intramolecular oxidative addition