Article | REF: AF6520 V1

Actinide speciation using synchrotron radiation

Authors: Eric SIMONI, Christophe DEN AUWER

Publication date: July 10, 2005

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3. Coordination polyhedron

The ability of actinyl oxocations to accept one or more ligands (mono or polydentate) in the equatorial plane (figure 6 a) depends largely on steric and electronic effects. Among these ligands, those with donor oxygen atoms have been extensively studied. Hydroxyl, carbonate and phosphate groups are the main donor groups

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Coordination polyhedron