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Article | REF: AF6520 V1

Actinide speciation using synchrotron radiation

Authors: Eric SIMONI, Christophe DEN AUWER

Publication date: July 10, 2005

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4. Chemical bond analysis

The following example aims to examine the role of 5f orbitals in the formation of the bond between an actinide ion and the ligands ferricyanide [Fe III (CN) 6 ] 3- and ferrocyanide [Fe II (CN) 6 ] 4- . The Fe(CN) 6 entities, with octahedral geometry , can bind to various metal ions such as the transition metals d

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