Article | REF: RE234 V1

Polymer Electrolytes for Lithium Metal Batteries

Authors: Renaud BOUCHET, Trang N.T. PHAN

Publication date: February 10, 2015

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4. Dry polymer electrolytes based on block copolymers

Solid electrolyte block copolymers comprise an A block, which ensures ion conduction, and a B block, which provides the material's mechanical strength thanks to its high T g value. The choice of the conductive block is essentially based on POE, which forms either the main linear backbone or the pendant grafts of block A. The main architectures of POE-based block copolymers, shown in figure 1 , correspond to either AB diblocks or BAB triblocks.

Linear and grafted block copolymer electrolyte architectures
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Dry polymer electrolytes based on block copolymers