Article | REF: P1111 V2

BioMolecular Crystallography From phases determination to final structure

Author: Jean CAVARELLI

Publication date: December 10, 2018, Review date: October 23, 2020

You do not have access to this resource.
Click here to request your free trial access!

Already subscribed? Log in!


Français

3. Using anomalous diffusion

The interaction of X-rays with a given atom j is modeled by a scattering factor f j which characterizes the scattering of the atom, taking that of a free electron as the unit. Under many conditions, f j is a real number, i.e. there is no phase difference between the wave scattered by the atom and that scattered by a free electron (Thompson scattering). In reality, the electrons of an atom are not free, but are distributed in orbitals of given energies, and the atom presents absorption discontinuities corresponding to the excitation of deep electronic layers. The approximations of classical theory are no longer justified if the incident X-ray energy is close to the atom's absorption threshold. A resonance phenomenon is triggered, resulting in a phase change of...

You do not have access to this resource.

Exclusive to subscribers. 97% yet to be discovered!

You do not have access to this resource.
Click here to request your free trial access!

Already subscribed? Log in!


The Ultimate Scientific and Technical Reference

A Comprehensive Knowledge Base, with over 1,200 authors and 100 scientific advisors
+ More than 10,000 articles and 1,000 how-to sheets, over 800 new or updated articles every year
From design to prototyping, right through to industrialization, the reference for securing the development of your industrial projects

This article is included in

Analysis and Characterization

This offer includes:

Knowledge Base

Updated and enriched with articles validated by our scientific committees

Services

A set of exclusive tools to complement the resources

Practical Path

Operational and didactic, to guarantee the acquisition of transversal skills

Doc & Quiz

Interactive articles with quizzes, for constructive reading

Subscribe now!

Ongoing reading
Using anomalous diffusion