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11. Possible link between dynamics and thermodynamics
11.1 Adam-Gibbs equation: entropy model of the glass transition
A link between the dynamic behavior and thermodynamic characteristics of glass-forming liquids emerges from what has been described above.
Strong liquids have an Arrhenian dynamic behavior and exhibit a small value of ΔC p at T g .
Brittle liquids have a very super-arrhenic dynamic behavior and generally exhibit a large value of ΔC p at T g .
For these fragile compounds, the Kauzmann temperature T K is usually close to...
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Possible link between dynamics and thermodynamics
Above Tg: dynamic heterogeneity and non-exponential relaxations
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