Article | REF: M2241 V1

Copper pyrometallurgy and electrorefining

Authors: Pierre BLAZY, El-Aid JDID

Publication date: December 10, 2001

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2. Electro-refining

The use of copper as an electrical conductor and its suitability for wire drawing require high-purity copper in excess of 99.95% Cu. Blister copper, after being cast and fire-refined, forms the soluble anode that yields Cu 2+ ions in sulfuric solution. These are deposited in a metallic state under the action of a direct electric current on a copper cathode.

2.1 Theoretical basis

According to Faraday's law, the quantity deposited Q (in g) is a function of current intensity I (in A) and time t (in h). The operation is performed with a certain efficiency η, and the relationship is written :

Q = 1.186 η It

...

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