Article | REF: M3624 V1

Cast steel production

Author: Jean-Marcel MASSON

Publication date: March 10, 2007

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5. Desulfurization

5.1 Chemical reaction

The extraction of sulfur from liquid steel necessarily involves the formation of stable sulfides. Thermodynamic data show the advantage of calcium sulfide (CaS) over other sulfides (MnS, FeS...). But calcium oxide (CaO) is also very stable. Desulfurization can therefore only take place by destabilizing the oxide (CaO) and creating thermodynamic conditions favorable to CaS precipitation (figure 13 ).

Equilibrium M, S. Free enthalpy of sulfide formation
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