Article | REF: K1260 V2

Supported Chemistry on Solid Phase

Author: Géraldine GOUHIER

Publication date: September 10, 2018

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2. Supports

This bibliography focuses on linear polymeric carbon supports, especially three-dimensional ones. Insoluble inorganic supports exist but are less widely exploited.

2.1 Linear skeletons

Linear backbone polymers are soluble in certain organic solvents, enabling reactions to be carried out in homogeneous media, without diffusion problems, with equal accessibility of all supported reaction sites and classical kinetics. What's more, immobilized substrates can be characterized by standard analytical techniques. Finally, polymer precipitation by addition of a non-solvent makes filtration possible. However, precipitation is not always total and selective, sometimes leading to separation and purification problems.

The linear polymers most commonly...

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