Article | REF: K90 V1

Molecular structures

Author: Bernard VALEUR

Publication date: November 10, 2004

You do not have access to this resource.
Click here to request your free trial access!

Already subscribed? Log in!


2. Bonding moments. Dipole moments of molecules

When two bonded atoms have different electronegativities (see article Properties of the elements ), the more electronegative atom carries a negative partial charge and the other atom an equal but positive partial charge, hence the existence of a dipole moment carried by the bond, called the bonding moment. This parameter defines the partial ionic character of a covalent bond.

The partial ionic character is the ratio (expressed as a %) of the actual dipole moment µ (bonding moment) to the dipole moment µ i that would be observed if the electron were totally transferred to the most electronegative atom.

We would then be dealing with an ionic bond and the atoms would carry the full charges + │e │ and - │e │, instead of the partial charges...

You do not have access to this resource.

Exclusive to subscribers. 97% yet to be discovered!

You do not have access to this resource.
Click here to request your free trial access!

Already subscribed? Log in!


The Ultimate Scientific and Technical Reference

A Comprehensive Knowledge Base, with over 1,200 authors and 100 scientific advisors
+ More than 10,000 articles and 1,000 how-to sheets, over 800 new or updated articles every year
From design to prototyping, right through to industrialization, the reference for securing the development of your industrial projects

This article is included in

Characterization and properties of matter

This offer includes:

Knowledge Base

Updated and enriched with articles validated by our scientific committees

Services

A set of exclusive tools to complement the resources

Practical Path

Operational and didactic, to guarantee the acquisition of transversal skills

Doc & Quiz

Interactive articles with quizzes, for constructive reading

Subscribe now!

Ongoing reading
Bonding moments. Dipole moments of molecules