Article | REF: AF6046 V1

Homogeneous Reactors for Radical Polymerization. Design and Operation

Authors: Alain DURAND, Sandrine HOPPE, Dimitrios MEIMAROGLOU, Christophe SERRA, Rabih RACHET, James WILSON

Publication date: April 10, 2020, Review date: November 25, 2021

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2. Kinetic diagram. Instantaneous" distribution of degrees of polymerization

2.1 Kinetic diagram of radical polymerization in a homogeneous medium

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2.1.1 Usual assumptions and approximations

We will restrict ourselves to monomers with a single carbon-carbon double bond reactive in free-radical polymerization. The most general typical kinetic scheme involves seven types of chemical processes: initiation, propagation, depropagation, termination, intermolecular transfers, intramolecular transfer/migration and β-scission (Table 2 ). The...

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Kinetic diagram. Instantaneous" distribution of degrees of polymerization
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