Article | REF: J1110 V1

General chemical kinetics - Mechanistic modeling

Author: Guy-Marie CÔME

Publication date: September 10, 1995

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5. Conclusion

In this chapter, General Chemical Kinetics, two methodologies for modeling chemical reaction kinetics have been proposed.

In the first article Experimental kinetics, the construction of a reaction scheme is based on the kinetic analysis of experimental results. Empirical kinetic laws are then assigned to each reaction and identified by comparison with experimental values. In principle, this method can be applied to any category of reactive system.

In this second article [J 1 110] Elementary reactions and reaction mechanisms, the approach to kinetic modeling is much more fundamental, since it is based on the achievements of transition state theory. It is thus possible to identify the main kinetic factors that need to be controlled during experimentation, to obtain the mathematical form of elementary kinetic laws and to estimate...

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