4. Modeling kinetic constants
4.1 Drawing up a reaction diagram
4.1.1 Principle and theoretical approach
When studying the thermal decomposition of a material, in order to establish the reaction scheme to be implemented on a material scale, it is advisable to rely on a decomposition chemistry that is globally understood by the analysis of pyrolysis and decomposition gases, as an approach based solely on the observed mass loss is insufficient to select one of several possible reaction schemes.
To understand the phenomena...
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Modeling kinetic constants
Bibliography
Software tools
ThermaKin. University of Maryland http://www.enfp.umd.edu/
Netzsch Component kinetics. NETZSCH-Gerätebau GmbH Headquarters, Wittelsbacherstrasse 42, 95100 Selb, Germany http://www.therm-soft.com/english/compkin.htm
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Events
International Association of Fire Safety Science's International Symposium of Fire Safety Science, held every 4 years http://www.iafss.org
Fire and Materials Conference, held every 2 years in San Francisco (USA) http://www.intersciencecomms.co.uk
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Standards and norms
- Sécurité incendie. Vocabulaire - ISO 13943 - 2008
- Reaction to fire tests – Heat output, smoke development rate and mass loss rate – Part 1: Heat flow (conical calorimeter method) - ISO 5660-1 - 2002
- Standard Test Method for Decomposition Kinetics by Thermogravimetry - ASTM E1641 - 2007
- Plastics – Thermogravimetry (TG) of polymers – Part 2: Determination of activation energy - ISO 11358-2 - 2005
Directory
Organizations – Federations – Associations (non-exhaustive list)
The International Association for Fire Safety Science (IAFSS) http://www.iafss.org
GDR CNRS research group n° 2864 "Forest fires and compartment fires". http://perso.ensem.inpl-nancy.fr/Anthony.Collin/GDR2864/
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