Article | REF: AF6507 V1

Organometallic chemistry - Application to homogeneous catalysis

Author: Yves JEANNIN

Publication date: October 10, 2000

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3. Olefin metathesis

Olefin metathesis is a particularly surprising reaction that has no equal in organic chemistry. It leads to various industrial applications. It involves crossing the four groups attached to two olefins, recomposing them to give two other olefins:

This reaction can be catalyzed in various ways. Tungsten hexachloride WCl 6 in admixture with the reducing agent Al2Cl4(

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Olefin metathesis