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Article | REF: AF6503 V1

Organometallic chemistry - Hydrogen ligand and corresponding derivatives

Author: Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015

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3. Acidity of the hydrogen atom bonded to a metal atom

The first known metal-hydrogen bonded compounds are [HCo(CO) 4 ] and [H 2 Fe(CO) 4 ]. These hydride ligands correspond, most of the time, to a bond polarity métalδ+​ Hδ− , rarely to métalδ-​ Hδ+ . In water, this translates into acidity....

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Acidity of the hydrogen atom bonded to a metal atom
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