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2. Polyelectronic systems
2.1 General
The hydrogen atom and the molecular ion
are the only two systems whose eigenstates are known exactly. For all other systems, we obtain Hamiltonians containing electrostatic electron-electron interaction terms that make it impossible to solve Schrödinger's equation analytically. Such a phenomenon is very common in physics, as static systems of interacting particles generally...
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Polyelectronic systems
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