Article | REF: AF4040 V1

Formalism and principles of thermodynamics

Authors: Louis SCHUFFENECKER, Jean-Noël JAUBERT, Roland SOLIMANDO

Publication date: January 10, 1999

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4. First principle of thermodynamics

Thermodynamics, like the other so-called "exact" physical sciences (electromagnetism, mechanics...), is built on a number of postulates inspired by experimental observations. Some of these are characteristic of thermodynamics and are of particular importance: these are the "principles".

4.1 Conservative balances

The phenomenological approach to the physical sciences is based on a fundamental premise:

Extensive conservative state properties exist, i.e. they have constant values throughout the Universe.

(The Universe being defined as the whole (system) U...

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First principle of thermodynamics