Article | REF: AF3640 V1

Crystallization and polymorphism - Description of the phenomenon

Author: Michel BAUER

Publication date: April 10, 2004

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4. Elements of crystallography

4.1 General

Simple bodies, inorganic molecules (usually ionic: ClNa, CO₃Ca, etc.) and organic molecules (neutral or in the form of salts) exist in the solid state in the form of crystals characterized by long-range order. This translates into the repetition in three-dimensional space of a pattern of atoms, ions or molecules, which, from a mathematical point of view, translates into a translation operation. A comprehensive understanding of polymorphism and crystal morphology requires an in-depth study of crystallography as the science of the spatial organization of atoms, ions and molecules (see box).

The beginnings of crystallography

If we started the history of polymorphism with Klaproth, we should in fact acknowledge...

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Elements of crystallography